Friday, October 20, 2017

Effect of Gamma Irradiation on Polytetrafluoroethylene




Effect of Gamma Irradiation on Polytetrafluoroethylene


Polytetrafluoroethylene (PTFE) is a synthetic polymer of tetrafluoroethylene. A sample of this material was left in intimate contact with a 1 microcurie radioisotope source of Cesium (Cs-137) for 2 weeks.



Control sample showing intact edges and opacity with minimal granularity





Irradiated sample shows unraveling of edges.



Gamma irradiation frees fluorine and depolymerizes (more accurately photoinduced polymer degradation: photolysis / photodisassociation) the PTFE into granules.

The gamma ray energies emitted by the radioisotope equal 661keV.




Control sample showing smooth, homogeneous surface and edges.